|
|Section2= |Section3= |Section7= |Section8= }} Ammonium hydrogen fluoride is the inorganic compound with the formula NH4HF2 or NH4F·HF. It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass-etchant and an intermediate in a once-contemplated route to hydrofluoric acid. == Structure == Ammonium bifluoride, as its name indicates, contains a bifluoride, or hydrogen(difluoride) anion: HF2−. This centrosymmetric triatomic anion features the strongest known hydrogen bond, with a F−H length of 114 pm. and a bond energy greater than 155 kJ mol−1.〔Emsley, J. (1980) ''Very strong hydrogen bonds'', Chemical Society Reviews, 9, 91–124. 〕 In solid ()(), each ammonium cation is surrounded by four fluoride centers in a tetrahedron, with hydrogen-fluorine hydrogen bonds present between the hydrogen atoms of the ammonium ion and the fluorine atoms. Solutions contain tetrahedral ()+ cations and linear ()− anions. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Ammonium bifluoride」の詳細全文を読む スポンサード リンク
|